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Controlled Preparation of Functional Hyperbranched Polymers and Their Applications in Bioscience  
Controlled Preparation of Functional Hyperbranched Polymers and Their Applications in Bioscience
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资料大小: 136K
所属学科: 分子表征
来源: 2009先进纤维与聚合物材料国际学术会议(ICAFPM,10.21-10.24,上海)
简介:
Benefitingfromtheirhighlybranchedarchitecture,hyperbranchedpolymershaveattractedmuchattentioninrecentyears.Here,severaldifferentapproaches,suchasA2+BB2’polycondensation,ring-openingpolymerization,proton-transferpolymerizationandhybridpolymerization,havebeenusedtopreparefunctionalhyperbranchedpolymers.Thearchitecturesandpropertiesofhyperbranchedpolymerscanbesuccessfullycontrolledbychangingvariousexperimentalparameters,includingthereactiontemperature,themixingsolventandthecatalystconcentration.Thesupramolecularinteractionhasalsobeenintroducedtocontrolthearchitectureofpolymerchains.Importantly,somenovelstimuli-responsivepolymers,suchasthethermo-,pH-,orthermo/pH/dual-responsivehyperbranchedpolymers,aresynthesized.Finally,theapplicationofthesefunctionalhyperbranchedpolymersinbioscience,especiallyforthegenetransfectionanddrugdelivery,hasbeenbrieflydiscussed.Thestructureoffunctionalhyperbranchedpolymersisdesignedtobemultifunctionalbyequippingwithbiodegradability,nontoxicity,stimuli-responsiveability,highlybranchedcompactarchitecture,andabundantfunctionalend-groups,whichmakesthefunctionalhyperbranchedpolymersaspromisingcarriersindrugdeliveryandgenetransfection.
作者: ZHU Xinyuan
上传时间: 2010-04-15 14:38:34
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