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Preparation and properties of silane modified waterborne polyurethane adhesive  
Preparation and properties of silane modified waterborne polyurethane adhesive
资料类型: PDF文件
关键词: waterborne  polyurethane  silane  coupling  agent  modification  interfacial  
shear  strength  
资料大小: 1234K
所属学科: 分子表征
来源: ICAFPM 2011先进纤维与聚合物材料国际学术会议(2011.8.15~17,上海)
简介:
Theenvironmentalfriendlywaterbornepolyurethane(WPU)hasbeenwidelyusedinmanyfieldsbecauseofitsexcellentchemicaladhesion.Inthisstudy,WPUemulsionwaspreparedbycondensationreactionfromrawmaterialstoformpre-polymerandfollowedbyneutralizingandemulsifying.ThentheWPUemulsionwasblockedwithsilanecouplingagent.Thechemicalstructure,thermalstabilityandparticlesizeofresultantPUweretestedbyfouriertransforminfrared(FTIR)spectra,thermogravimetry(TG)analysisandlaserparticleanalyzer.Theadhesivepropertiywascharacterizedbytheinterfacialshearstrength(IFSS)betweenPUmatrixandUHMWPEfiber.SomeparticularcharacteristicabsorptionpeaksinFTIRspectrumprovedsiliconehadbeensuccessfullyintroducedinPUmolecularchainandformedSi-O-Sistructure.TGanalysisshowedthattheheatresistanceofresultantPUwassignificantlyimprovedaftersilanemodification.TheaverageparticlesizeofsilanemodifiedPUbecamelargerandthesizedistributionbecamewiderwithincreasingofthesilanecontent.TheIFSSbetweenmodifiedPUandUHMWPEfiberincreasedwithincreasingofsilanecontent.Whenthesilanecontentwas2%,thegeneralperformanceofmodifiedPUwouldbemorebalancedand50%increasementintheadhesivepropertywasgot.
作者: ZHU Liliang, YU Junrong, LI Yan, CHEN Lei, ZHU Jing, HU Zuming
上传时间: 2011-09-29 15:22:33
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whq134    2017-10-07 11:32:39
Preparation and
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