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Space Charge Suppression Effect of Mgo Nanoparticles in Low Density Polyethylene  
Space Charge Suppression Effect of Mgo Nanoparticles in Low Density Polyethylene
资料类型: PDF文件
关键词: magnesia  (  mg0)  polyethylene  insulation  breakdown  strength  
pulsed  electroacoustic(pea)  
资料大小: 99K
所属学科: 分子表征
来源: 第六届亚欧研讨会上处理和性能增强聚合物会议文集(2013.6.2-6 武汉)
简介:
IthasbeenreportedthatadditionofasmallamountofMgonanoparticlestolow-densitypolyethylene(LDPE)canofferthepolymerexcellentelectricalinsulatingpropertiescl],thereforeMgO/LDPEnano-compositesbecomethepromisingcandidatematerialsforcablesinalong-distanceandhigh-voltagedirect-currentpowertransmission.Inthiswork,theMgonanoparticlescoatedwithvinyltris(2-methoxyethoxy)silanewereblendedwithLDPEusingamixerfromHAAKE.Itwasshownbythepulsedelectroacoustic(PEA)methodthatMgonanoparticlessignificantlyreducedthespacechargeinjectionandaccumulateinthepolymerinsulationmaterials,andincreasedthebreakdownstrength.AmodelofelectricchargetrapsproducedbythepermanentandinduceddipolemomentshasbeenproposedbyTanakaeralc2].ThedeeptrapsprovidedbyinducedpotentialwellofMgonanoparticleswerethoughtpossiblytosuppressthespacechargeformation.Onthebasisofthismodel,bytakingtheinterfacepropertiesbetweenthefillersandthematrixintoaccount,andcombiningwithpercolationeffectsofthefillers,wefurtherstudiedtheeffectofdispersiondensityofMgonanoparticlesinLDPE.Theresultsshowedtheelectrictrapswerebroadenedduetotheexistenceoftheinterfacelayer.Itseemedthatinterspacingbetweentheparticlesshouldbewithinacertainrangeinordertoachieveeffectivespacechargesuppression,whichwasconsistentwiththeexperimentalresults.Thedielectricconstantofthenanoparticlewasthekeyfactoraffectingthedepthandwidthofthetraps,thuswedofurtherexperimentsusingthenanoparticleswithdifferentdielectricconstantstoverifytheresults
作者: S. T. Ju, M. J. Chen, H. Zhang, Z. Zhang
上传时间: 2013-07-02 16:39:18
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