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Macroporous Activated Carbon Fibers from Rayon Precursors Impregnated with Phosphoric Acid  
Macroporous Activated Carbon Fibers from Rayon Precursors Impregnated with Phosphoric Acid
资料类型: PDF文件
关键词: Macroporous  Activated  Carbon  Fibers  
资料大小: 584K
所属学科: 分子表征
来源: 2005年新型纤维与聚合物材料国际学术会议(10.19-10.21,上海)
简介:
Thepreparationofrayon-basedmacroporousactivatedcarbonfibers(RACFs)fromrayonprecursorsimpregnatedwithphosphoricacid(H3PO4)andactivatedbywatervaporwasstudiedinthispaper.AnovelACFscontainingmanymacropores(poresize>50nm)weresuccessfullyobtainedwithhighcarbonyieldsbyusingproperimpregnationratiosofH3PO4andthesemacroporousACFsalsoexhibitedahighadsorptionabilitydeterninedbuBET.Infaredspectroscopy(IR)weremainlyappliedtoinvestigatethepyrolysisprocessofrayonpercursorsimpregnatedwithH3PO4.Inaddition,P-containingfunctionalities,whichshouldprobablybeacidphosphatesorpolyosphates,canbeobservedonthesurfaceoftheresultingACFs.ItcanbeconcludedfromSEMobservationthattheconcentrationofH3PO4inprengnationstronglyinfluencedthesurfacemorphlulgyandtheporoustextureoftheresultingACFs.
作者: Zhihai Zhang Qilin Wu Aifang Yu Ding Pan
上传时间: 2007-08-09 17:52:18
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