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Interfacial Curvature Effects in The Self-assembly and Responsiveness in Polypeptide-based Star and Triblock Copolymers
Interfacial Curvature Effects in The Self-assembly and Responsiveness in Polypeptide-based Star and Triblock Copolymers
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This study involves the bottom-up design and tunability of responsive, peptide-based block
opolymers. The self-assembly of amphiphilic block copolymers is dictated primarily by the alance between the hydrophobic core volume and the hydrophilic corona. In these studies,mphiphilic triblock and star copolymers containing poly(lysine) (PK) and poly(glutamic acid) (PE)were synthesized and their solution properties studied using dynamic light scattering, circular
ichroism spectroscopy and transmission electron microscopy. These materials exhibit