Morphology and thermal property of PP/ M-PEEAM composite，2009先进纤维与聚合物材料国际学术会议（ICAFPM，10.21-10.24，上海）-中国聚合物网,论文下载

Morphology and thermal property of PP/ M-PEEAM composite

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PP/ M-PEEAM composite morphology thermal property rheology

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分子表征

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2009先进纤维与聚合物材料国际学术会议（ICAFPM，10.21-10.24，上海）

简介：

Zincoxide,hexanedioicacid,PEG，caprolactamandMDIwerechosenasrawmaterialstosynthesizepoly(etheresteramidecontainingzinc)(M-PEEAM).ThePP/M-PEEAMcompositeandfiberwerethenpreparedbyblendingM-PEEAMandPP.TherheologicalandthermalpropertiesofthePP/M-PEEAMcompositewereinvestigated,andthemicrostructureofthePP/M-PEEAMfiberwasobservedbySEM.TherheologicalstudyindicatedthecomplexviscosityofthePP/M-PEEAMcompositereducedwiththeincreaseofthefrequencywithinacertainrange,whichexplainsthatthePP/M-PEEAMcompositeshowedobviouslyrheologicalbehaviorofpseudoplasticfluid.DSCstudyindicatedthecompositehadalargeendothermicpeakat166-167℃andtwosmallendothermicpeakat50℃and218℃,respectively,implyingthatPPwasincompatiblewithM-PEEAM.However,theM-PEEAMcontentinthecompositehadnotmuchinfluenceonthemeltingtemperatureofPP.SEMshowedthatPP/M-PEEAMblendsgaveatwo-phasestructurewithsphericallyM-PEEAMdispersedinPPmatrixandthesizeofdispersionphaseincreasedwithincreasingM-PEEAMcontent.

作者：

GUO Jing, HUANG Wenfei, WANG Qiao

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2010-01-18 16:05:29

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